In-situ FTIR spectroelectrochemical study of chromium hexacyanoferrate on glassy carbon electrode
Data(s) |
1998
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Resumo |
Chromium hexacyanoferrate (CrHCF) modified grassy carbon electrode (GC) in different electrolytes was studied by cyclic voltammetry and in situ FTIR spectroelectrochemistry. The results indicate that the behavior of CrHCF firm can be understood in term of two structures: Cr1/3Cr(III)Fe(II)(CN), and MCr(III)Fe(II)(CN)(6). Besides,the film exists in amorphous state: the outer layer is porous film, while the inner layer is relatively compact. According to the electrochemical reaction of CrHCF, the lattice can contract and expand with the cations' diffusion. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Bo AL;Lin XQ.In-situ FTIR spectroelectrochemical study of chromium hexacyanoferrate on glassy carbon electrode,CHINESE CHEMICAL LETTERS,1998,9(9):851-854 |
Palavras-Chave | #PRUSSIAN BLUE |
Tipo |
期刊论文 |