In-situ FTIR spectroelectrochemical study of chromium hexacyanoferrate on glassy carbon electrode


Autoria(s): Bo AL; Lin XQ
Data(s)

1998

Resumo

Chromium hexacyanoferrate (CrHCF) modified grassy carbon electrode (GC) in different electrolytes was studied by cyclic voltammetry and in situ FTIR spectroelectrochemistry. The results indicate that the behavior of CrHCF firm can be understood in term of two structures: Cr1/3Cr(III)Fe(II)(CN), and MCr(III)Fe(II)(CN)(6). Besides,the film exists in amorphous state: the outer layer is porous film, while the inner layer is relatively compact. According to the electrochemical reaction of CrHCF, the lattice can contract and expand with the cations' diffusion.

Identificador

http://202.98.16.49/handle/322003/22559

http://www.irgrid.ac.cn/handle/1471x/156014

Idioma(s)

英语

Fonte

Bo AL;Lin XQ.In-situ FTIR spectroelectrochemical study of chromium hexacyanoferrate on glassy carbon electrode,CHINESE CHEMICAL LETTERS,1998,9(9):851-854

Palavras-Chave #PRUSSIAN BLUE
Tipo

期刊论文