Self-assembly of a water chain with tetrameric and decameric clusters in the channel of a mixed-valence (CuCuII)-Cu-I complex
Data(s) |
2007
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Resumo |
The reaction of Cu(BF4)(2) with pyridine-2,6-dicarboxylic acid (H(2)pydc) and trans-1,2-bis(4-pyridyl)ethylene (bpe) under hydrothermal conditions afforded a porous mixed-valence (CuCuII)-Cu-I coordination polymer. Coexistence of tetrameric and decameric water clusters within the channels of the complex leads to a novel water chain. The metal-organic framework provides both hydrophilic and hydrophobic environments for stabilizing the clusters and retains its integrity upon dehydration and rehydration. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Hu NH;Li ZG;Xu JW;Jia HQ;Niu JJ.Self-assembly of a water chain with tetrameric and decameric clusters in the channel of a mixed-valence (CuCuII)-Cu-I complex,CRYSTAL GROWTH & DESIGN,2007 ,7(1):15-17 |
Palavras-Chave | #ORGANIC SUPRAMOLECULAR COMPLEX #CRYSTAL HOST #COORDINATION POLYMERS #(H2O)(N) #HEXAMER #ACID #ICE #SPECTROSCOPY #MOLECULES #PENTAMER |
Tipo |
期刊论文 |