Efficient synthesis of highly substituted pyrrolin-4-ones via PIFA-mediated cyclization reactions of enaminones
| Data(s) |
2007
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|---|---|
| Resumo |
A convenient and efficient synthesis of highly substituted pyrrolin-4-ones is developed via the PIFA-mediated cyclization reactions of readily available enaminones, and a mechanism involving sequential cleavage of N-C bond, formation of new N-C bond, intramolecular addition reaction, and benzilic acid type rearrangement is proposed. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Huang J;Liang YJ;Pan W;Yang Y;Dong DW.Efficient synthesis of highly substituted pyrrolin-4-ones via PIFA-mediated cyclization reactions of enaminones,ORGANIC LETTERS,2007 ,9(26):5345-5348 |
| Palavras-Chave | #NITROGEN-BRIDGED HETEROCYCLES #PEPTIDE HYBRID LIGAND #MHC PROTEIN HLA-DR1 #ONE-POT SYNTHESIS #S BOND FORMATION #OLEFIN AMIDOHYDROXYLATION #POLYVALENT IODINE #CRYSTAL-STRUCTURE #FORMAL SYNTHESIS #RING-SYSTEMS |
| Tipo |
期刊论文 |
