Synthesis of Arm-6 polystyrene by atom transfer radical polymerization
Data(s) |
2007
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Resumo |
A new initiator for atom transfer radical polymerization (ATRP), (Cl-2 HCCOO)(3) -C-6 H-3, (TrDCAP),has been designed and successfully synthesized. ATRP of styrene was carried out by using TrDCAP as hexafunctional initiator and the CuCl/bpy catalyst at 130 degrees C in 30% THF via core-first strategy. The Arm-6 PS-AAP was synthesized by etherealization of Arm-6 PS and 4-(4'-methoxyphenylazomethine) phenol (AAP). The initiator and the architectures of the Arm-6 PS were confirmed by H-1-NMR, FT-IR, UV-Vis and GPC. |
Identificador | |
Idioma(s) |
中文 |
Fonte |
Yu XF;Zhang G;Shi TF;An LJ.Synthesis of Arm-6 polystyrene by atom transfer radical polymerization,ACTA POLYMERICA SINICA,2007 ,(6):577-581 |
Palavras-Chave | #LIVING ANIONIC-POLYMERIZATION #POLYMERS #STAR #ATRP #TRANSFORMATION #COMBINATION #COPOLYMERS #BLOCK |
Tipo |
期刊论文 |