Liquid-liquid extraction of protactinium(V) using tri-iso-octylamine


Autoria(s): Ding, HJ (Ding, H. J.); Niu, YN (Niu, Y. N.); Xu, YB (Xu, Y. B.); Yang, WF (Yang, W. F.); Yuan, SG (Yuan, S. G.); Qin, Z (Qin, Z.); Wu, XL (Wu, X. L.)
Data(s)

3920

Resumo

Solvent extraction of protactinium with tri-iso-octyl-amine (TIOA) in xylene, benzene, carbon tetrachloride and chloroform from HCl, HF, HNO3, HClO4 and H2SO4 media was studied using Pa-233 as a radiotracer. The extraction efficiencies of protactinium were determined as a function of shaking time, concentrations of mineral acids in aqueous phase, extractant concentrations and diluents in organic phase. The extraction mechanism was discussed. The results show that the extracted species in the organic phase is [(R3N-H)(n)Pa(OH)(x)Cl-y(5-x-y)].

Identificador

http://ir.impcas.ac.cn/handle/113462/6015

http://www.irgrid.ac.cn/handle/1471x/132694

Idioma(s)

英语

Fonte

Ding, HJ (Ding, H. J.); Niu, YN (Niu, Y. N.); Xu, YB (Xu, Y. B.); Yang, WF (Yang, W. F.); Yuan, SG (Yuan, S. G.); Qin, Z (Qin, Z.); Wu, XL (Wu, X. L.).Liquid-liquid extraction of protactinium(V) using tri-iso-octylamine ,JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,39203,272(2):263-266

Palavras-Chave #CHEMICAL-PROPERTIES #AQUEOUS-SOLUTION #ELEMENT-105 #SEPARATION #FLUORIDE #CHLORIDE #NIOBIUM #AMINE #PA #TA
Tipo

期刊论文