One-step synthesis of a cyclic 2,17-dioxo3,3](4,4 `)biphenylophane and first preparation of a microporous polymer network from a macrocyclic precursor by cyclotrimerization


Autoria(s): Samanta, Suman Kalyan; Preis, Eduard; Lehmann, Christian W; Goddard, Richard; Bag, Saientan; Maiti, Prabal K; Brunklaus, Gunther; Scherf, Ullrich
Data(s)

2015

Resumo

One-step synthesis of a cyclic 2,17-dioxo3,3](4,4') biphenylophane (MC) was achieved in high yield; its structure was verified by single crystal X-ray analysis. As a first example, a microporous polymer network was formed from macrocycle MC via acid-catalysed cyclotrimerization yielding a BET surface area of ca. 570 m(2) g(-1).

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/51740/1/che_comm_51-43_9046_2015.pdf

Samanta, Suman Kalyan and Preis, Eduard and Lehmann, Christian W and Goddard, Richard and Bag, Saientan and Maiti, Prabal K and Brunklaus, Gunther and Scherf, Ullrich (2015) One-step synthesis of a cyclic 2,17-dioxo3,3](4,4 `)biphenylophane and first preparation of a microporous polymer network from a macrocyclic precursor by cyclotrimerization. In: CHEMICAL COMMUNICATIONS, 51 (43). pp. 9046-9049.

Publicador

ROYAL SOC CHEMISTRY

Relação

http://dx.doi.org/ 10.1039/c5cc01654a

http://eprints.iisc.ernet.in/51740/

Palavras-Chave #Physics
Tipo

Journal Article

PeerReviewed