Response to ``Comment on `Frequency-domain stimulated and spontaneous light emission signals at molecular junctions''' J. Chem. Phys. 142, 137101 (2015)]


Autoria(s): Harbola, Upendra; Agarwalla, Bijay Kumar; Mukamel, Shaul
Data(s)

2015

Resumo

In a recent work [U. Harbola, B. K. Agrawalla, and S. Mukamel, J. Chem. Phys. 141, 074107 (2014)], we have presented a superoperator (Liouville space) diagrammatic formulation of spontaneous and stimulated optical signals from current-carrying molecular junctions. We computed the diagrams that contribute to the spontaneous light emission SLE (fluorescence and Raman) signal using a diagrammatic method which clearly distinguishes between the Raman and the fluorescence contributions. We pointed out some discrepancies with the work of Galperin, Ratner and Nitzan (GRN) [M. Galperin, M. A. Ratner and, A. Nitzan, J. Chem. Phys. 130, 144109 (2009)]. In their response [M. Galperin, M. A. Ratner and A. Nitzan, “Comment on‘ Frequency-domain stimulated and spontaneous light emission signals at molecular junctions’” [J. Chem. Phys. 141, 074107 (2014)], J. Chem. Phys. 142, 137101 (2015)] to our work, GRN have argued that there are no differences in the choice of Raman diagrams in both works. Here we reply to their points and show where the differences exist.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/51515/1/jou_che_phy-142_13_2015.pdf

Harbola, Upendra and Agarwalla, Bijay Kumar and Mukamel, Shaul (2015) Response to ``Comment on `Frequency-domain stimulated and spontaneous light emission signals at molecular junctions''' J. Chem. Phys. 142, 137101 (2015)]. In: JOURNAL OF CHEMICAL PHYSICS, 142 (13).

Publicador

AMER INST PHYSICS

Relação

http://dx.doi.org/10.1063/1.4916524

http://eprints.iisc.ernet.in/51515/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed