An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes


Autoria(s): Nagaraju, Chinta; Prasad, Kavirayani R
Data(s)

2014

Resumo

A novel ring contraction/rearrangement sequence leading to functionalized 2,8-oxymethano-bridged di- and triquinane compounds is observed in the reaction of various substituted 1-methyl-4-isopropenyl-6-oxabicylo3.2.1]octan-8-ones with Lewis acids. The reaction is novel and is unprecedented for the synthesis of di- and triquinane frameworks.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/50367/1/ang_che_int_edi_53-41_10997_2014.pdf

Nagaraju, Chinta and Prasad, Kavirayani R (2014) An Unusual Ring-Contraction/Rearrangement Sequence for Making Functionalized Di- and Triquinanes. In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53 (41). pp. 10997-11000.

Publicador

WILEY-V C H VERLAG GMBH

Relação

http://dx.doi.org/ 10.1002/anie.201407680

http://eprints.iisc.ernet.in/50367/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed