Ethyl 6-methyl-2-sulfanylidene-4-[4(trifluoromethyl)phenyl]-1,2,3,4-tetrahyd ropyrimidine-5-carboxylate


Autoria(s): Nayak, Susanta K; Venugopala, KN; Govender, Thavendran; Kruger, Hendrik G; Maguire, Glenn EM; Row, Guru TN
Data(s)

23/05/2011

Resumo

The title compound, C(15)H(15)F(3)N(2)O(2)S, adopts a conformation with an intramolecular C-H center dot center dot center dot pi interaction. The dihedral angles between the planes of the 4-(trifluoromethyl) phenyl and ester groups with the plane of the six-membered tetrahydropyrimidine ring are 81.8 (1) and 16.0 (1)degrees, respectively. In the crystal structure, intermolecular N-H center dot center dot center dot S hydrogen bonds link pairs of molecules into dimers and N-H center dot center dot center dot O interactions generate hydrogen-bonded molecular chains along the crystallographic a axis.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/41665/1/Ethyl_6-methyl-2.pdf

Nayak, Susanta K and Venugopala, KN and Govender, Thavendran and Kruger, Hendrik G and Maguire, Glenn EM and Row, Guru TN (2011) Ethyl 6-methyl-2-sulfanylidene-4-[4(trifluoromethyl)phenyl]-1,2,3,4-tetrahyd ropyrimidine-5-carboxylate. In: Acta Crystallographica Section E, 67 (Part 7). O1559-U1766.

Publicador

International Union of Crystallography

Relação

http://journals.iucr.org/e/issues/2011/07/00/si2356/si2356bdy.html

http://eprints.iisc.ernet.in/41665/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed