Synthesis based on cyclohexadienes .23. Total synthesis of 5-epi-pupukean-2-one


Autoria(s): Kaliappan, Krishna; Rao, Subba GSR
Data(s)

21/11/1997

Resumo

A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes which involves stereoselective alkylation of a bicyclooctenone derivative and a decarboxylative 5-exo-trig radical cyclisation as the key steps in the total synthesis of 5-epi-pupukean-2-one.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/38518/1/Synthesis_based_on_cyclohexadienes.pdf

Kaliappan, Krishna and Rao, Subba GSR (1997) Synthesis based on cyclohexadienes .23. Total synthesis of 5-epi-pupukean-2-one. In: Perkin Transactions 1 (22). pp. 3387-3392.

Publicador

Royal Society of Chemistry

Relação

http://pubs.rsc.org/en/Content/ArticleLanding/1997/P1/a704312k

http://eprints.iisc.ernet.in/38518/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed