Synthesis and characterization of poly(vinyl acetate peroxide)


Autoria(s): Jayanthi, S; Kishore, K
Data(s)

21/03/1996

Resumo

Poly(vinyl acetate peroxide) (PVACP) was prepared from vinyl acetate by free-radical-initiated oxidative polymerization. The polyperoxide was isolated and characterized by different spectroscopic methods. The extreme instability of PVACP was demonstrated by FTIR spectroscopy. The H-1- and C-13-NMR studies show the irregularities in the polyperoxide chain due to the cleavage reactions of the propagating peroxide radical. Thermal degradation studies using differential scanning calorimetry revealed that PVACP degrades at a lower temperature and the heat of degradation is in the same range as reported for other vinyl polyperoxides. (C) 1996 John Wiley & Sons, Inc.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/37604/1/Synthesis_and_Characterization.pdf

Jayanthi, S and Kishore, K (1996) Synthesis and characterization of poly(vinyl acetate peroxide). In: Journal of Applied Polymer Science, 59 (12). 1887 -1890 .

Publicador

John Wiley and Sons

Relação

http://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291097-4628%2819960321%2959:12%3C1887::AID-APP10%3E3.0.CO;2-P/abstract;jsessionid=C9756F3DE8ADE7E71BCB6461A85CB07E.d02t01?systemMessage=Wiley+Online+Library+will+be+disrupted+14+May+from+10-12+BST+for+mon

http://eprints.iisc.ernet.in/37604/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed