A β,β,β-trialkoxyethyllithium stable towards fragmentation: a carboxyl protected acetic acid dianion equivalent
Data(s) |
04/07/1944
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Resumo |
The novel alkyllithium 1b is not only intriguingly stable towards fragmentation, but also a synthetically useful reagent, complementing current carboxylic ester enolate methodology. Its design is based on interesting mechanistic principles, and harnesses the known stability of the 2,4,10-trioxaadamantane framework. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/36092/1/beta.pdf Chandrasekhar, S and Roy, CD (1944) A β,β,β-trialkoxyethyllithium stable towards fragmentation: a carboxyl protected acetic acid dianion equivalent. In: Tetrahedron, 50 (27). 8099 -8102. |
Publicador |
Elsevier Science |
Relação |
http://dx.doi.org/10.1016/S0040-4020(01)85292-3 http://eprints.iisc.ernet.in/36092/ |
Palavras-Chave | #Organic Chemistry |
Tipo |
Journal Article PeerReviewed |