Some sulphoxide complexes of iron
Data(s) |
01/04/1970
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Resumo |
Diphenyl sulphoxide(DPSO) and dimethyl sulphoxide(DMSO) complexes of iron(II) having the composition [Fe(DPSO)6](ClO4)2, Fe(DPSO)2Cl2, Fe(DPSO)3Br2, Fe(DPSO)4I2, [Fe (DMSO)3Cl2]. DMSO and [Fe(DMSO)3Br2]. DMSO and DPSO complexes of iron(III), Fe(DPSO)2 Cl3 have been prepared and their physico-chemical properties studied. Their magnetic moments at room temperature show them to be spin-free complexes. The i.r. spectra reveal that oxygen is the donor atom in all the complexes. The electronic spectra of iron(II) complexes indicate octahedral coordination for the metal ion. A salt like structure [Fe(DPSO)4Cl2][FeCl4], is suggested for the iron (III) complex, where the cationic species has distorted octahedral structure while the anionic species has tetrahedral structure. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/28197/1/some.pdf Prabhakaran, CP and Patel, CC (1970) Some sulphoxide complexes of iron. In: Journal of Inorganic and Nuclear Chemistry, 32 (4). pp. 1223-1228. |
Publicador |
Elsevier B.V |
Relação |
http://dx.doi.org/10.1016/0022-1902(70)80118-X http://eprints.iisc.ernet.in/28197/ |
Palavras-Chave | #Inorganic & Physical Chemistry |
Tipo |
Journal Article PeerReviewed |