Nature, stability and bonding of the peroxy group in peroxy titanium compounds


Autoria(s): Patel, CC; Jere, GV
Data(s)

01/09/1963

Resumo

Some physicochemical properties of peroxy titanium compounds are explained by assigning a strained triangular ring structure to the peroxy titanyl group, with a bent and reduced overlap of the O---O bonding orbitals. The stability of the peroxy group is found to depend on the stability of the other ligands. The decreasing order of stability of the peroxy group in the compounds is as: oxalato > meleato > malonato > sulphato > peroxide of titanium.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/28191/1/Nature.pdf

Patel, CC and Jere, GV (1963) Nature, stability and bonding of the peroxy group in peroxy titanium compounds. In: Journal of Inorganic and Nuclear Chemistry, 25 (9). pp. 1155-1159.

Publicador

Elsevier Science

Relação

http://dx.doi.org/10.1016/0022-1902(63)80137-2

http://eprints.iisc.ernet.in/28191/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed