Sequence distribution in Acrylonitrile-methylacrylate random copolymers by N.M.R spectroscopy

The sequence distribution studies on the acrylonitrile-methylmethacrylate copolymer of high methylmethacrylate (M) content (30%<M<75%) by NMR studies is reported in this paper. A tentative assignment has been made forthe isolated M centered unit AMA, 2M centered units MMA (or AMM) based on the shape of the peaks observed for methixy and a-methyl protons. The presence of MMM type of triad sequences is indicated by the pattern of a-methyl protons.