Control of Regiochemistry in Photodimerization through Micellar Preorientational Effect: 2-Substituted Naphthalenes


Autoria(s): Ramesh, V; Ramamurthy, V
Data(s)

1984

Resumo

Photodimerization of 2-substituted naphthalenes in organic solvents has been well explored. In contrast to their behavior in organic solvents, in anionic and cationic micellar media enhanced reactivity and pronounced regioselectivity are observed. Reactivity enhancement in micellar media is attributed to the local concentration effect. Enhanced reactivity in CTAC and DTAC compared to CTAB micelles is attributed to the counterion effect, and the regioselective photodimerization observed in anionic and cationic micelles leading exclusively to the cis dimer or the products derived therefrom is rationalized on the basis of the preorientational effect of micelles.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/24045/1/9.pdf

Ramesh, V and Ramamurthy, V (1984) Control of Regiochemistry in Photodimerization through Micellar Preorientational Effect: 2-Substituted Naphthalenes. In: Journal of organic chemistry, 49 (3). pp. 536-539.

Publicador

American Chemical Society

Relação

http://pubs.acs.org/doi/abs/10.1021/jo00177a029

http://eprints.iisc.ernet.in/24045/

Palavras-Chave #Organic Chemistry
Tipo

Journal Article

PeerReviewed