L-Arginine L-aspartate
Data(s) |
1982
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Resumo |
C6HxsN40 +.C4H6NO~-, monoclinic, P2,,a = 5.511 (3), b = 8.438 (4), c = 15.265 (9) A, fl = 97.9 (I) °, D,, -- 1.467 (8) (flotation), D c = 1.452 Mg m -a, Z = 2. The structure has been refined to a final R value of 0.044 for 1226 independent counter-measured reflections. The conformation of the arginine molecule is different from those previously observed, whereas the conformation of the aspartate ion is similar to that found in L-aspartic acid, DL-aspartic acid and L-lysine L-aspartate. The unlike molecules aggregate into separate alternating layers and the a-amino and acarboxylate groups in the arginine layer are periodically brought into close proximity in a 'headto-tail' arrangement. There exist a specific ion-pair interaction involving electrostatic attraction and two nearly parallel N-H...O hydrogen bonds between the guanidyl group and the a-carboxylate group of the aspartate ion. |
Formato |
application/pdf |
Identificador |
http://eprints.iisc.ernet.in/21805/1/fulltext.pdf Salunke, DM and Vijayan, M (1982) L-Arginine L-aspartate. In: Acta Crystallographica Section B, 38 . pp. 1328-1330. |
Publicador |
International Union of Crystallography |
Relação |
http://journals.iucr.org/b/issues/1982/04/00/issconts.html http://eprints.iisc.ernet.in/21805/ |
Palavras-Chave | #Molecular Biophysics Unit |
Tipo |
Journal Article PeerReviewed |