Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants


Autoria(s): Zhang, Xingguang; Du, Aijun; Zhu, Huaiyong; Jia, Jianfeng; Wang, Jun; Ke, Xuebin
Data(s)

01/10/2014

Resumo

Enhanced catalytic performance of zeoltes via the plasmonic effect of gold nanoparticles has been discovered to be closely correlated with the molecular polarity of reactants. The intensified polarised electrostatic field of Na+ in NaY plays a critical role in stretching the C=O bond of aldehydes to improve the reaction rate.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/78049/

Publicador

Royal Society of Chemistry

Relação

http://eprints.qut.edu.au/78049/2/78049.pdf

DOI:10.1039/C4CC03225J

Zhang, Xingguang, Du, Aijun, Zhu, Huaiyong, Jia, Jianfeng, Wang, Jun, & Ke, Xuebin (2014) Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants. Chemical Communications, 50, pp. 13893-13895.

Direitos

Copyright 2014 Royal Society of Chemistry

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #030601 Catalysis and Mechanisms of Reactions #090402 Catalytic Process Engineering #100708 Nanomaterials #Surface plasmon #zeolite #molecular polarity #acetalisation
Tipo

Journal Article