A novel protecting group methodology for syntheses using nitroxides
| Data(s) |
2013
|
|---|---|
| Resumo |
The methoxyamine group represents an ideal protecting group for the nitroxide moiety. It can be easily and selectively introduced in high yield (typically >90%) to a range of functionalised nitroxides using FeSO4.7H2O and H2O2 in DMSO. Its removal is readily achieved under mild conditions in high yield (70-90%) using mCPBA in a Cope-type elimination process. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://eprints.qut.edu.au/66694/2/66694.pdf DOI:10.1039/C3CC46146G Chalmers, Benjamin, Morris, Jason, Fairfull-Smith, Kathryn, Grainger, Richard, & Bottle, Steven (2013) A novel protecting group methodology for syntheses using nitroxides. Chemical Communications, 2013(88), pp. 10382-10384. |
| Direitos |
Copyright 2013 Royal Society of Chemistry |
| Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
| Palavras-Chave | #030501 Free Radical Chemistry |
| Tipo |
Journal Article |
