Infrared study of the adsorption of formic acid on silica-supported copper and oxidised copper catalysts
Data(s) |
1991
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Resumo |
Infrared spectra are reported of formic acid adsorbed at 300 K on a reduced copper catalyst (Cu/SiO2) and a copper surface which had been oxidised by exposure to nitrous oxide. Formic acid was weakly adsorbed on the silica support. Ligation of formic acid to the copper surface occurred only on the reduced catalyst. Dissociative adsorption resulted in the formation of unidentate formate on the oxidised catalyst. The presence of reduced copper metal instigated a rapid reorientation to a bidentate formate species. |
Formato |
application/pdf |
Identificador | |
Publicador |
Royal Society of Chemistry |
Relação |
http://eprints.qut.edu.au/61970/1/Faraday_transactions_online_%2C_87_%289%29%2C_p._1491.pdf DOI:10.1039/FT9918701491 Millar, Graeme J., Rochester, Colin H., & Waugh, Kenneth C. (1991) Infrared study of the adsorption of formic acid on silica-supported copper and oxidised copper catalysts. Journal of the Chemical Society, Faraday Transactions, 87(9), pp. 1491-1496. |
Direitos |
Copyright 1991 Royal Society of Chemistry Restrictions on further re-use and further distribution |
Fonte |
School of Chemistry, Physics & Mechanical Engineering; Institute for Future Environments; Science & Engineering Faculty |
Palavras-Chave | #030601 Catalysis and Mechanisms of Reactions #catalyst #infrared #copper #formic acid |
Tipo |
Journal Article |