rac-3-exo-Ammonio-7-anti-carboxytricyclo-[2.2.10.2,6]heptane-3-endo-carboxylate


Autoria(s): Smith, Graham; Wermuth, Urs D.; Jenkins, Ian D.
Data(s)

2012

Resumo

The racemic title compound, C9H11NO4 . H2O, a tricyclic rearranged aminonorbornane dicarboxylic acid is a conformationally rigid analogue of glutamic acid and exists as an ammonium-carboxylate zwitterion, with the bridghead carboxylic acid group anti-related. In the crystal, intermolecular N-H...O and O-H...O hydrogen-bonding interactions involving the ammonium, carboxylic acid and water donor groups with both water and carboxyl O-atom acceptors give a three-dimensional framework structure.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/49816/

Publicador

Blackwell

Relação

http://eprints.qut.edu.au/49816/1/URSCAGE.pdf

DOI:10.1107/S1600536812016236

Smith, Graham, Wermuth, Urs D., & Jenkins, Ian D. (2012) rac-3-exo-Ammonio-7-anti-carboxytricyclo-[2.2.10.2,6]heptane-3-endo-carboxylate. Acta Crystallographica E, 68(5), o1468-o1469.

Direitos

Copyright 2012 International Union of Crystallography

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #030000 CHEMICAL SCIENCE #crystal structure #aminobornane carboxylic acid #hydrogen bonding
Tipo

Journal Article