catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]


Autoria(s): Smith, Graham; Wermuth, Urs D.; Williams, Michael L.
Data(s)

01/12/2011

Resumo

In the structure of the title compound, [C8H11LiO4(H2O)2]n the distorted tetrahadral LiO4 coordination sphere comprises two water molecules and two carboxyl O-donors from separate bridging cis-2-carboxycyclohexane-1-carboxylate monoanions [Li-O range, 1.887(4)-1.946(3)A], giving chain substructures which extend along (010). Water-water and water-carboxyl O-H...O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional layered structure extending across (011).

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/46959/

Publicador

International Union of Crystallography (IUCr)

Relação

http://eprints.qut.edu.au/46959/1/CHDCLI.PDF

DOI:10.1107/S1600536811045077

Smith, Graham, Wermuth, Urs D., & Williams, Michael L. (2011) catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]. Acta Crystallographica Section E : Structure Reports Online, 67(12), m1658-m1658.

Direitos

Copyright 2011 please consult author

Fonte

Chemistry; Faculty of Science and Technology

Palavras-Chave #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #crystal structure #hydrogen-bonding #metal complex #lithium
Tipo

Journal Article