Poly[aqua([mu]3-2-hydroxy-5-nitrobenzoato-[kappa]3O1:O1':O2)rubidium]
Data(s) |
17/09/2011
|
---|---|
Resumo |
In the structure of title compound [Rb2(C7H4NO2)2(H2O)2]n the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxylate groups of the 5-nitrosalicylate ligands. The coordination about each Rb is completed by a monodentate water molecule and a phenolic O donor which gives a bridging extension [Rb-O range 3.116(7)-3.135(5)A]. The two-dimensional polymeric structure is stabilized by intermolecular water O-H...O(carboxyl) hydrogen bonds and weak inter-ring pi--pi interactions [minimum ring centroid separation, 3.620(4)A]. |
Formato |
application/pdf |
Identificador | |
Publicador |
Blackwell Publishing on behalf of IUCr |
Relação |
http://eprints.qut.edu.au/46110/1/46110a.pdf DOI:10.1107/S1600536811037561 Smith, Graham, Wermuth, Urs D., & Williams, M. L. (2011) Poly[aqua([mu]3-2-hydroxy-5-nitrobenzoato-[kappa]3O1:O1':O2)rubidium]. Acta Crystallographica. Section E : Structure Reports Online, 67, m1400-m1400. |
Direitos |
Copyright International Union of Crystallography 2011 |
Fonte |
Chemistry; Faculty of Science and Technology |
Palavras-Chave | #030606 Structural Chemistry and Spectroscopy #crystal structure #5-nitrosalicylic acid #rubidium #complex polymer |
Tipo |
Journal Article |