2-(4-Aminophenyl)-1-phenyldiazenium 2,4,6-trinitrophenolate


Autoria(s): Smith, Graham; Wermuth, Urs D.; White, Jonathon M.
Data(s)

2011

Resumo

In the structure of the title salt, C12H12N3+ C6H2N3O7-, the diazenyl group of the 4-(phenyldiazenyl)aniline molecule is protonated and forms a hydrogen bond with the phenolate O acceptor of the picrate anion. Structure extension occurs through two symmetrical inter-ion three-centre amine N---H...O,O'(nitro) hydrogen-bonding associations [graph set R2/1(4)] giving a convoluted two-dimensional network structure.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/40952/

Publicador

Blackwell Publishing on behalf of IUCr

Relação

http://eprints.qut.edu.au/40952/1/PAZANPIC.PDF

DOI:10.1107/S1600536811008968

Smith, Graham, Wermuth, Urs D., & White, Jonathon M. (2011) 2-(4-Aminophenyl)-1-phenyldiazenium 2,4,6-trinitrophenolate. Acta Crystallographica. Section E : Structure Reports Online, 67(4), o878-o878.

Direitos

Copyright 2011 IUCr & The Authors

This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Fonte

Chemistry; Faculty of Science and Technology

Palavras-Chave #crystal structure #hydrogen bonding #proton transfer #picrates #aniline yellow
Tipo

Journal Article