Controlled rate thermal analysis of sepiolite


Autoria(s): Frost, Ray L.; Kristof, Janos; Horvath, Erzsebet
Data(s)

01/09/2009

Resumo

CRTA technology offers better resolution and a more detailed interpretation of the decomposition processes of a clay mineral such as sepiolite via approaching equilibrium conditions of decomposition through the elimination of the slow transfer of heat to the sample as a controlling parameter on the process of decomposition. Constant-rate decomposition processes of non-isothermal nature reveal changes in the sepiolite as the sepiolite is converted to an anhydride. In the dynamic experiment two dehydration steps are observed over the ~20-170 and 170-350°C temperature range. In the dynamic experiment three dehydroxylation steps are observed over the temperature ranges 201-337, 337-638 and 638-982°C. The CRTA technology enables the separation of the thermal decomposition steps.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/28325/

Publicador

Akademiai Kiado Rt.

Relação

http://eprints.qut.edu.au/28325/1/c28325.pdf

DOI:10.1007/s10973-009-0321-z

Frost, Ray L., Kristof, Janos, & Horvath, Erzsebet (2009) Controlled rate thermal analysis of sepiolite. Journal of Thermal Analysis and Calorimetry, 98(2), pp. 423-428.

Direitos

Copyright 2009 Akademiai Kiado, Budapest, Hungary

Fonte

Faculty of Science and Technology; School of Physical & Chemical Sciences

Palavras-Chave #030603 Colloid and Surface Chemistry #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #030606 Structural Chemistry and Spectroscopy #030601 Catalysis and Mechanisms of Reactions #attapulgite, sepiolite, palygorskites, thermal analysis, CRTA, thermogravimetry
Tipo

Journal Article